3.0.CO;2-4" target="_blank" >doi:10.1002/1099-1409(200011)4:7<649::AID-JPP233>3.0.CO;2-4">
 

Title

Compounds in the series from boron subphthalocyanine to boron subnaphthalocyanine

Document Type

Article

Publication Date

2000

Department/School

Chemistry

Abstract

The four compounds in the series from chloro[subphthalocyaninato]boron(III) to chloro[subnaphthalocyaninato]boron(III) were synthesized in a one-pot reaction. To obtain a more soluble set of compounds, the mixture was then reacted with the sodium salt of trihexylsilanol. This mixture was separated by chromatography to provide trihexylsiloxy[subphthalocyaninato] boron(III), trihexylsiloxy [SubN(1)P(2)]boron(III), trihexylsiloxy[SubN(2)P(1)]boron(III) and trihexylsiloxy [subnaphthalocyaninato]boron(III). These compounds were characterized by H-1 NMR, EI-MS and UV-vis. They show interesting spectral features in the visible region. Copyright (C) 2000 John Wiley & Sons, Ltd.